Synthesis of 2-chromanone-fused [3.2.0] bicycles through a phosphine-mediated tandem [3 + 2] cyclization/intramolecular Wittig reaction

A phosphine-mediated tandem [3 + 2] cyclization/intramolecular Wittig reaction of alkynone is described. 2-Chromanone-fused bicyclo[3.2.0]heptenones were synthesized in moderate to high yields with remarkably high regio- and diastereoselectivities.