淀粉
钯
催化作用
变性淀粉
铃木反应
席夫碱
可重用性
多糖
化学
化学工程
高分子化学
有机化学
材料科学
软件
计算机科学
工程类
程序设计语言
作者
Xinjuan Li,Zhangquan Zhou,Yanan Wang,Jiaxin Dong,Xianbin Jia,Zhiguo Hu,Qingcong Wei,Weiwei Zhang,Yuqin Jiang,Jiaojiao Zhang,Yahao Dong
标识
DOI:10.1016/j.ijbiomac.2023.123596
摘要
Starch can be used in diverse fields because it is a readily available, non-toxic polysaccharide with adaptable functionality and biodegradability. In this study, taking the aforementioned characteristics into consideration, we designed a modified starch (Starch-SB), which serves as supporting material for palladium stabilization. This new air and moisture-stable robust palladium composite [Starch-SB-Pd(II)] was characterized by FT-IR, XRD, TGA, XPS, SEM, EDX, TEM, CP/MAS 13C NMR, and ICP-MS analytical techniques. The catalytic studies exhibit high activity (up to 99 %) and stability in Suzuki cross-coupling reactions for this starch supported catalytic system under mild conditions (lower reaction temperature and green solvents) because of the cooperative interactions of multifunctional capturing sites on starch (Schiff base, hydroxy and amine groups) with palladium species. The experiments on reusability demonstrate that Starch-SB-Pd(II), which was prepared from functionalized starch, could be readily recycled several cycles through centrifugation. Moreover, we proposed a possibly multifunctional complex structure. This work presents an appealing and intriguing pathway for the utilization of polysaccharide as crucial support in green chemical transformations.
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