阳离子聚合
化学
萃取(化学)
吸附
烯烃纤维
烷基
共价键
三嗪
化学稳定性
化学工程
有机化学
组合化学
聚合物
工程类
作者
Wei‐Rong Cui,Wei Xu,Yi-Ru Chen,Kai Li,Weibin Qiu,Yibao Li,Jian‐Ding Qiu
标识
DOI:10.1016/j.jhazmat.2022.130603
摘要
Efficient extraction of radioactive 99TcO4- from strong acid/base solutions by porous adsorbents is extremely desirable but remains a great challenge. To overcome the challenge, here we report the first example of an olefin-linked cationic covalent organic framework (COF) named BDBI-TMT with excellent acid, base and radiation stability is synthesized by integrating robust imidazolium salt-based linkers with triazine building blocks. BDBI-TMT shows an ultra-fast adsorption kinetics (equilibrium is reached within 1 min) and an excellent ReO4- (a non-radioactive surrogate of 99TcO4-) capture capacity of 726 mg g-1, which can be attributed to the abundance of precisely tailored imidazolium salt-based units on the highly accessible pore walls of the ordered pore channels. Furthermore, the formation of the highly conjugated bulky alkyl skeleton enhances the hydrophobicity of BDBI-TMT, which significantly improves not only the affinity toward ReO4-/99TcO4- but also the chemical stability, allowing selective and reversible extraction of ReO4-/99TcO4- even under extreme conditions. This work demonstrates the great potential of olefin-linked cationic COFs for ReO4-/99TcO4- extraction, providing a new avenue to construct high-performance porous adsorbents for radionuclide remediation.
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