Sustainable polylactic acid spunlace nonwoven fabrics with lignin/zinc oxide/water-based polyurethane composite coatings

In this paper, polylactic acid spunlace nonwoven fabrics were coated with lignin/zinc oxide/water-based polyurethane composite formulations, including five different ratios of lignin and zinc oxide, via a film applicator and thermally cured. The coated and thermally cured nonwoven fabrics were tested in terms of color values, tensile strength, abrasion resistance, ultraviolet protection, hydrophobicity, antibacterial activity, air, and vapor permeability properties. Characterization studies were conducted by FTIR, DSC, TGA, XRD, and SEM. The ultraviolet protection factor of 215.47 and a water contact angle of 90.27° were obtained with the fabric coated with WPU-1:5 formulation. Nonwoven fabric coated with the WPU-1:5 formulation showed evident antibacterial activity against S. aureus and E. coli bacteria as 89 % and 100 %, respectively. With the addition of lignin/ZnO into water-based polyurethane coating paste, PLA nonwoven fabric exhibited improved antibacterial activity, tensile strength, abrasion resistance, and ultraviolet light protection performance. However, composite coatings decreased air and vapor permeability and hydrophobicity of fabrics, but acceptable results were obtained. The results indicate that polylactic acid nonwoven fabrics, when treated with lignin/ZnO/WPU composite coatings, exhibit enhanced mechanical and functional properties, rendering them promising for applications in protective medical textiles.