化学
异构化
钴
催化作用
钌
Diels-Alder反应
碳纤维
双键
药物化学
有机化学
材料科学
复合数
复合材料
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2022-11-23
卷期号:34 (01): 23-28
被引量:2
标识
DOI:10.1055/s-0042-1753142
摘要
Abstract In this Account, I report the start of my independent career, concerning cobalt-catalyzed carbon–carbon bond formations and the twenty-year long journey to the final decision to abandon the field. Some highlights, such as the regiodiverse neutral Diels–Alder reaction and the cobalt versus ruthenium-catalyzed Alder-ene reaction are discussed. Besides such highlights, also some aspects that led to unpleasant experiences are reported from a personal point of view. 1 Introduction 2 The Regiodivergent Neutral-Diels–Alder Reaction 3 The Chemoselective [2+2+2] Cyclotrimerization of Alkynes and Nitriles 4 The Cobalt-Catalyzed Alder-ene Reaction 5 The Isomerization of Carbon–Carbon Double Bonds 6 The Final Chord 7 Conclusion
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