连接器
苄胺
共价键
光催化
化学
共价有机骨架
可见光谱
材料科学
光化学
催化作用
有机化学
光电子学
计算机科学
操作系统
作者
Kanghui Xiong,Yuexin Wang,Fulin Zhang,Xia Li,Xianjun Lang
标识
DOI:10.1016/j.apcatb.2022.122135
摘要
Myriad endeavors have shifted towards covalent organic frameworks (COFs) for their aptitude in visible light photocatalysis. Herein, three β-ketoenamine COFs with different linker lengths, i.e., TpPa-COF, TpBD-COF, and TpDT-COF, were synthesized from 1,3,5-triformylphloroglucinol and 1,4-benzenediamine, 4,4'-biphenyldiamine, and 4,4''-p-terphenyldiamine, respectively. With the shortest linker, a noticeable conversion of benzylamine was observed by TpPa-COF photocatalysis. By prolonging the linker length, TpBD-COF performed a better conversion of benzylamine, which might be due to more suitable redox potentials than TpPa-COF. However, with the longest linker, TpDT-COF resulted in a lower conversion than TpBD-COF, which might be ascribed to the slightly inferior optoelectronic properties. With a moderate linker length, TpBD-COF convincingly delivered the best photocatalytic activity for the violet light-driven aerobic oxidation of amines. This work sheds light on the dimension of linker length in designing more active COF photocatalysts.
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