Improved Quality of InN Thin Films Using a Thin InGaN Compressive Strain Gradient Layer

材料科学 光致发光 蓝宝石 光电子学 薄膜 基质(水族馆) 拉曼光谱 位错 衍射 带隙 图层(电子) 电子迁移率 光学 纳米技术 复合材料 激光器 地质学 海洋学 物理
作者
Satish Shetty,Andrian V. Kuchuk,Fernando Maia de Oliveira,Serhii Kryvyi,Chen Li,Paul Minor,Mohammad Zamani-Alavijeh,Nirosh M. Eldose,Subhashis Das,Dinesh Baral,Yuriy I. Mazur,H. Alan Mantooth,Gregory J. Salamo,Satish Shetty,Andrian V. Kuchuk,Fernando Maia de Oliveira,Serhii Kryvyi,Chen Li,Paul Minor,Mohammad Zamani-Alavijeh
出处
期刊:Crystal Growth & Design [American Chemical Society]
卷期号:24 (15): 6115-6123
标识
DOI:10.1021/acs.cgd.4c00095
摘要

High-quality InN has significant opportunities for exciting and impactful electronic and photonic applications. These applications rely on growth techniques that produce high-quality InN thin films. To achieve the fabrication of InN semiconductor thin films with a low density of misfit and threading dislocations, we report on a growth technique that utilizes composition and strain gradients to limit the propagation of defects into InN grown on a GaN/sapphire substrate. The growth technique we have investigated utilizes a compressively strained gradient transition layer to limit the propagation of threading dislocations from the GaN buffer. Reflection high-energy electron diffraction, high-resolution X-ray diffraction, Raman spectroscopy, photoluminescence, and Hall measurements were employed to evaluate the effectiveness of the gradient transition layer to improve the quality of InN thin films. The outcome is that for InN films grown on partially graded InxGa1–xN (x → 0 to 29%), when compared with InN grown directly on a GaN substrate, we observed about a 40% decrease in edge dislocations, a 50% increase in photoluminescence, and a 20% increase in mobility. When compared to a sharp strain boundary, a linear strain gradient offers threading dislocations the opportunity to reduce the energy of the system more by leaving the system than by propagating into the strained region.

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