Organic redox flow batteries in non-aqueous electrolyte solutions

Redox flow batteries (RFBs) are gaining significant attention due to the growing demand for sustainable energy storage solutions. In contrast to conventional aqueous vanadium RFBs, which have a restricted voltage range resulting from the use of water and vanadium, the utilization of redox-active organic molecules (ROMs) as active materials broadens the range of applicable liquid media to include non-aqueous electrolyte solutions. The extended voltage range of non-aqueous media, exceeding 2 V, facilitates the establishment of high-energy storage systems. Additionally, considering the higher cost of non-aqueous solvents compared to water, the objective in developing non-aqueous electrolyte solution-based organic RFBs (NRFBs) is to efficiently install these systems in a compact manner and explore unique applications distinct from those associated with aqueous RFBs, which are typically deployed for grid-scale energy storage systems. This review presents recent research progress in ROMs, electrolytes, and membranes in NRFBs. Furthermore, we address the prevailing challenges that require revolution, encompassing a narrow cell voltage range, insufficient solubility, chemical instability, and the crossover of ROMs. Through this exploration, the review contributes to the understanding of the current landscape and potential advancements in NRFB technology and encourages researchers and professionals in the energy field to explore this emerging technology as a potential solution to global environmental challenges.