Extraction Induced by Emulsion and Microemulsion Breaking for Metal Determination by Spectrometric Methods – A Review

This review focuses on extraction induced by the destabilization of emulsified systems combined with spectrometric techniques for metal analysis in oily samples. This approach is based on the formation and breaking of an emulsion (extraction induced by emulsion breaking – EIEB) or microemulsion (extraction induced by microemulsion breaking – EIMB) to transfer the analytes from the oil sample to the aqueous phase, which is separated in the process. Its simplicity, speed, and low cost have contributed to its growing popularity among researchers. However, the potential of EIEB and EIMB is far from being fully exploited. Therefore, this paper aims to provide relevant information to expand the applicability of these methods. The principle of the methods is discussed, and a brief description of emulsified systems is presented. The parameters affecting the extraction efficiency and calibration strategy are also critically discussed. Furthermore, the analytical applications of the methods are reviewed. Trends and opportunities in this field are also considered.