氮化硼
材料科学
纳米片
复合材料
复合数
热导率
环氧树脂
纳米颗粒
硼
磁场
聚合物
纳米技术
化学
物理
有机化学
量子力学
作者
Yifan He,Fengxia Kuang,Zhanxun Che,Fangyuan Sun,Kun Zheng,Jingnan Zhang,Xinyu Cao,Yuantai Ma
标识
DOI:10.1016/j.compositesa.2022.106933
摘要
The preparation of boron nitride nanosheet (BNNS)/polymer composite films with high out-of-plane thermal conductivity (K) remains a challenge. Here, we obtained BNNS/epoxy (EP) resin composite films with well aligned BNNSs exhibiting a high K in the out-of-plane direction through the careful optimization of the magnetic field strength. Firstly, magnetically responsive BNNSs (m-BNNSs) with a large surface area were prepared by loading Fe3O4 nanoparticles via in situ co-precipitation. Secondly, m-BNNSs were incorporated into EP to prepare well aligned m-BNNS/EP composites by controlling the intensity and direction of the magnetic field. The results show that the BNNSs are well oriented in the out-of-plane direction, resulting in a K as high as 14.55 Wm−1K−1 for 30.0- wt% BNNS loading, which is 4.5 times higher than that of unoriented films and 70 times higher than that of pure EP. This strategy can be extrapolated to obtain polymer composite films filled with other two-dimensional materials.
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