Crystal structure of μ3-tetrathioantimonato-tris[(cyclam)zinc(II)] tetrathioantimonate acetonitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetraazacyclotetradecane)

Reaction of Zn(ClO₄)₂·6H₂O with cyclam (cyclam = 1,4,8,11-tetra-aza-cyclo-tetra-decane, C₁₀H₂₄N₄) and Na₃SbS₄ in an aceto-nitrile/water mixture led to the formation of crystals of the title compound, [Zn₃(SbS₄)(C₁₀H₂₄N₄)₃](SbS₄)·2CH₃CN·2H₂O or [(Zn-cyclam)₃(SbS₄)₂](H₂O)₂(aceto-nitrile)₂. The set-up of the crystal structure is similar to that of [(Zn-cyclam)₃(SbS₄)₂]^.8H₂O reported recently [Danker et al. (2021 ▸). Dalton Trans. 50, 18107-18117]. The crystal structure of the title compound consists of three crystallographically independent Zn^II cations (each disordered around centers of inversion), three centrosymmetric cyclam ligands, one SbS₄ ^3- anion, one water and one aceto-nitrile mol-ecule occupying general positions. The aceto-nitrile mol-ecule is equally disordered over two sets of sites. Each Zn²⁺ cation is bound to four nitro-gen atoms of a cyclam ligand and one sulfur atom of the SbS₄ ^3- anion within a distorted square-pyramidal coordination. The cation disorder of the [Zn(cyclam)]²⁺ complexes is discussed in detail and is also observed in other compounds, where identical ligands are located above and below the [Zn(cyclam)]²⁺ plane. In the title compound, the building units are arranged in layers parallel to the bc plane forming pores in which the aceto-nitrile solvate mol-ecules are located. Inter-molecular C-H⋯S hydrogen bonding links these units to the SbS₄ ^3- anions. Between the layers, additional water solvate mol-ecules are present that act as acceptor and donor groups for inter-molecular N-H⋯O and O-H⋯S hydrogen bonding.