Temperature band of ordinary telecommunication optical fibers is −60...85°C. The developing fiber optic sensors which can work at higher temperatures, required to develop metal coated optical fibers. The Purpose of the work is a researching additional optical loss of copper alloy coated optical fibers which were drawn from low hydroxyl group contamination preforms at temperatures 20...800°C. It is reached that metal coated optical fiber worked at temperature 700°C for 7 hours, while the optical losses changed from 2 to 3 dB/km at the wavelength of λ = 1300 nm. It is not observed intensive growth of optical losses on hydroxyl groups at 800°C, which was observed in metal coated optical fiber when it was heated at 700°C.