微观结构
X射线光电子能谱
研磨
吸附
聚合
化学工程
吸附
材料科学
球磨机
纤维
高分子化学
复合材料
化学
聚合物
有机化学
工程类
作者
Emı́lia Csiszár,Erika Fekete
出处
期刊:Langmuir
[American Chemical Society]
日期:2011-06-09
卷期号:27 (13): 8444-8450
被引量:28
摘要
Cotton and linen fibers were ground in a ball-mill, and the effect of grinding on the microstructure and surface properties of the fibers was determined by combining a couple of simple tests with powerful techniques of surface and structure analysis. Results clearly proved that the effect of grinding on cotton fiber was much less severe than on linen. For both fibers, the degree of polymerization reduced (by 14.5% and 30.5% for cotton and linen, respectively) with a simultaneous increase in copper number. The increased water sorption capacity of the ground substrates was in good agreement with the X-ray results, which proved a less perfect crystalline structure in the ground samples. Data from XPS and SEM-EDS methods revealed that the concentration of oxygen atoms (bonded especially in acetal and/or carbonyl groups) on the ground surfaces increased significantly, resulting in an increase in oxygen/carbon atomic ratio (XPS data: from 0.11 to 0.14 and from 0.16 to 0.29 for cotton and linen, respectively). Although grinding created new surfaces rich in O atoms, the probable higher energy of the surface could not be measured by IGC, most likely due to the limited adsorption of the n-alkane probes on the less perfect crystalline surfaces.
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