聚丙烯
材料科学
弹性体
丙烯腈
复合材料
乙烯
色散(光学)
纳米尺度
金属
天然橡胶
化学工程
聚合物
高分子化学
共聚物
纳米技术
化学
冶金
有机化学
工程类
催化作用
光学
物理
作者
А. М. Магеррамов,Н. И. Курбанова,M. N. Bayramov,N. A. Alimirzoyeva,S. K. Ragimova,A. N. Nabiyeva
标识
DOI:10.1134/s2075113321030254
摘要
Using radiothermoluminescence (RTL), the molecular mobility features in the temperature range of 77–300 K were studied for the polypropylene (PP)/ethylene propylene diene elastomer SKEPT-4044 with NiO, Cu2O, and Fe3O4 nanoparticles (NPs) based on ABS-acrylonitrile butadiene or SCS-divinyl styrene matrices. It has been shown that the introduction of nanofillers in PP significantly affects the nature and temperature of γ- and β-relaxation processes, while the region of manifestation of the β process noticeably shifts to the region of low temperatures. Composites with Cu2O NPs have a higher β-transition temperature Tβ than composites with other NPs. It has been found that PP/SKEPT-4044 composites with Cu2O NPs with a dispersion of 11–15 nm and acrylonitrile butadiene thermoplastics have optimal frost resistance compared to other compositions.
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