共聚物
高分子化学
聚(N-异丙基丙烯酰胺)
摩尔质量
水溶液
差示扫描量热法
聚合物
聚合
木筏
低临界溶液温度
动态光散射
材料科学
化学工程
聚电解质
化学
物理化学
纳米技术
有机化学
热力学
纳米颗粒
工程类
物理
作者
Clémence Nadal,Stéphane Gineste,Olivier Coutelier,Audrey Tourrette,Jean‐Daniel Marty,Mathias Destarac
标识
DOI:10.1016/j.colsurfa.2022.128502
摘要
Block copolymers based on poly(vinylamine) and poly(N-isopropylacrylamide), PVAmm-b-PNIPAMn, were synthetized by hydrazinolysis of poly(N-vinylphthalimide) based copolymers, PVPIm-b-PNIPAMn, obtained by RAFT polymerization. The effect of molar mass and pH on the thermoresponsive and aggregation properties of these polymers in aqueous solution was studied with UV–vis spectroscopy, differential scanning calorimetry, NMR spectrometry, light and X-ray scattering experiments. For the first time it was demonstrated that at room temperature, these copolymers are prone to self-assemble and tend to form larger aggregates upon heating. Hence core-shell nanostructures with a dense PNIPAM core and a hydrophilic PVAm shell, were notably observed above Tc when pH < pKa.
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