发光
材料科学
氧气
蓝移
蓝宝石
分析化学(期刊)
持续发光
溅射
光致发光
溅射沉积
光电子学
纳米技术
光学
薄膜
化学
激光器
物理
热释光
有机化学
色谱法
作者
Yiyin Nie,Shujie Jiao,Shaofang Li,Hongliang Lü,Shuo Liu,Yang Song,Dongbo Wang,Shiyong Gao,Jinzhong Wang,Yongfeng Li
标识
DOI:10.1016/j.jallcom.2021.163431
摘要
In this work, the β-Ga2O3 films were fabricated by radio frequency magnetron sputtering on the c-plane sapphire substrates with the (2¯01) preferred orientation. The blue and green luminescence of β-Ga2O3 films have been systemically studied. By changing the concentration of intrinsic vacancies in β-Ga2O3 films through increasing oxygen flow rate during sputtering, the intensity of blue and green luminescence were modulated. The maximum value of the intensity ratio for green luminescence to blue luminescence reached to 433.37% when the oxygen flow rate arrived at 6 sccm. Combining experiments with density functional theory calculations, this work had proved the green luminescence in β-Ga2O3 mainly originated from the isolated gallium vacancies. While the isolated oxygen vacancies could not play the important roles in the blue emission independently. The blue luminescence most likely resulted from complex defects such as (VOI+VGaI)− or the optical transitions between VO and (VO, VGa). Thus, changing the concentration of intrinsic vacancies is highly effective for β-Ga2O3 to modulate the intensity of green luminescence and blue luminescence.
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