弹性体
硫化
材料科学
极限抗拉强度
聚合物
天然橡胶
单体
气相二氧化硅
复合材料
共聚物
填料(材料)
化学工程
高分子科学
工程类
作者
Jacob P. Brutman,Guilhem X. De Hoe,Deborah K. Schneiderman,Truyen N. Le,Marc A. Hillmyer
标识
DOI:10.1021/acs.iecr.6b02931
摘要
Most commercial elastomers, typified by vulcanized natural rubber, are cross-linked polymers and as such cannot easily be reprocessed or recycled. While some are derived from renewable resources, the majority are produced from petroleum feedstocks and do not easily degrade. In this study, renewable elastomers based on β-methyl-δ-valerolactone were produced using two different methodologies: (1) tandem copolymerization/cross-linking with a bis(six-membered cyclic carbonate); (2) cross-linking of a linear poly(β-methyl-δ-valerolactone) homopolymer with a free-radical generator. The mechanical properties of these materials were investigated; tensile strengths of up to 12 MPa and elongations of up to 2000% were observed. Inclusion of a filler (fumed silica) was used to enhance the performance of the elastomers without significant loss of elasticity, with some composites exhibiting tensile strengths nearly double that of the neat elastomer. Aqueous degradation studies indicated that the materials were capable of degradation in acidic and basic conditions at 60 °C. Moreover, these cross-linked elastomers can also be chemically recycled, yielding monomer in high purity and yield (>91% and 93%, respectively).
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