材料科学
水泥
镁
胶凝的
磷酸钾
硅酸盐水泥
抗压强度
吸水率
化学工程
热重分析
耐水性
磷酸镁
醋酸乙烯酯
聚合物
环氧乙烷
复合材料
冶金
有机化学
化学
工程类
共聚物
作者
Guangqing Chen,Yubing Du,Chuanren Wu,Yanbo Li,Yueyang Hu,Jianming Yang
标识
DOI:10.1680/jadcr.24.00162
摘要
Magnesium phosphate cement, which is widely used as a rapid repair cementitious material, has limitations in terms of water resistance. Extensive studies have confirmed that adding redispersible polymer powder (RPP) to ordinary Portland cement enhances its water resistance. This study thus investigates the effect of ethylene vinyl acetate-based RPP on the mechanical properties and water stability of magnesium potassium phosphate cement (MKPC). The findings indicate that incorporating 0.5% RPP in MKPC achieves the highest flexural and compressive strengths compared to samples without RPP. The addition of 0.5% RPP also results in the greatest water stability and lowest water absorption. Thermogravimetric and X-ray diffraction analysis reveal that 0.5% RPP promotes the formation of hydration products. As shown in scanning electron microscopy results, MKPC with 0.5% RPP exhibits larger, smoother and more fully formed hydration products. The RPP adsorbs on the magnesium oxide surface, reducing flowability and delaying the hydration process. In later stages, the film-forming effect of RPP establishes a spatial network structure with hydration products, thereby enhancing the water resistance of MKPC.
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