Tuning Oxygen Occupancy within Metal-Oxo Clusters for Enhancing Catalytic Activity of Zr-MOFs

sponsorship: We thank KU Leuven and Research Foundation - Flanders (FWO) for funding. C.S. (68090/11C9320N), and A.M. (1228622N) thank the FWO for fellowships. T.P.N.V. thanks FWO (G025624N and I002720N) for funding. We acknowledge Elettra Sincrotrone Trieste for providing access to its synchrotron radiation facilities (Project no. 20220131, A.M. as PI) and for financial support under the IUS internal project. Moreover, A.M. acknowledges the FWO for an extended research stay grant at the Elettra synchrotron facility (Grant no. V439222N). J.J.C., A.S.-D., and J.P.-J. are thankful for the grant PID2021-128128NB-I00, funded by MCIN/AEI/10.13039/501100011033 and by "ERDF A way of making Europe" and the Generalitat de Catalunya (2021SGR00110). A.S.-D. also acknowledges the Spanish Ministry of Universities and the European Union - Next Generation EU for their financial support through a Margarita Salas grant. A.S.-D. also acknowledges financial support from the "la Caixa" Foundation (ID 100010434) under the fellowship code LCF/BQ/PI24/12040012. (KU Leuven and Research Foundation - Flanders (FWO)|68090/11C9320N, FWO|1228622N, FWO|G025624N, FWO|I002720N, FWO|20220131, FWO|V439222N, IUS internal project, MCIN/AEI|PID2021-128128NB-I00, ERDF A way of making Europe, Generalitat de Catalunya|2021SGR00110, Spanish Ministry of Universities, European Union - Next Generation EU, The "la Caixa" Foundation|100010434, The "la Caixa" Foundation|LCF/BQ/PI24/12040012)