闪烁体
放射发光
闪烁
材料科学
纳米复合材料
光电子学
发光
纳米技术
光学
物理
探测器
作者
Andrea Erroi,Sara Mecca,Matteo L. Zaffalon,Isabel Frank,Francesco Carulli,Alessia Cemmi,Ilaria Di Sarcina,Doriana Debellis,Francesca Rossi,Francesca Cova,Kristof Pauwels,Michele Mauri,Jacopo Perego,Valerio Pinchetti,Angiolina Comotti,Francesco Meinardi,A. Vedda,Etiennette Auffray,Luca Beverina,Sergio Brovelli
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2023-08-28
卷期号:8 (9): 3883-3894
被引量:8
标识
DOI:10.1021/acsenergylett.3c01396
摘要
The use of scintillators for the detection of ionizing radiation is a critical aspect in many fields, including medicine, nuclear monitoring, and homeland security. Recently, lead halide perovskite nanocrystals (LHP-NCs) have emerged as promising scintillator materials. However, the difficulty of affordably upscaling synthesis to the multigram level and embedding NCs in optical-grade nanocomposites without compromising their optical properties still limits their widespread use. In addition, fundamental aspects of the scintillation mechanisms are not fully understood, leaving the scientific community without suitable fabrication protocols and rational guidelines for the full exploitation of their potential. In this work, we realize large polyacrylate nanocomposite scintillators based on CsPbBr3 NCs, which are synthesized via a novel room temperature, low waste turbo-emulsification approach, followed by their in situ transformation during the mass polymerization process. The interaction between NCs and polymer chains strengthens the scintillator structure, homogenizes the particle size distribution and passivates NC defects, resulting in nanocomposite prototypes with luminescence efficiency >90%, exceptional radiation hardness, 4800 ph/MeV scintillation yield even at low NC loading, and ultrafast response time, with over 30% of scintillation occurring in the first 80 ps, promising for fast-time applications in precision medicine and high-energy physics. Ultrafast radioluminescence and optical spectroscopy experiments using pulsed synchrotron light further disambiguate the origin of the scintillation kinetics as the result of charged-exciton and multiexciton recombination formed under ionizing excitation. This highlights the role of nonradiative Auger decay, whose potential impact on fast timing applications we anticipate via a kinetic model.