磷光
材料科学
碳化
光化学
荧光
纳米技术
猝灭(荧光)
聚合物
荧光粉
光电子学
化学
扫描电子显微镜
物理
复合材料
量子力学
作者
Chuan Zhen Huang,Qinbin Zhang,Yichuan Zhang,Mingming Guo
标识
DOI:10.1016/j.colsurfa.2023.131456
摘要
Carbonized polymer dots (CPDs) are proposed as a novel room temperature phosphorescence (RTP) materials that widely used in optoelectronic devices, bioimaging, especially in the field of information encryption and anti-counterfeiting due to their unique optical properties. However, achieving RTP emission under matrix-free conditions requires reasonable structural design to prevent the quenching of triplet excitons, which is very challenging. Herein, we proposed a facile, rapid and effective strategy to prepare matrix-free nitrogen and phosphorus co-doped CPDs (named Arg-CPDs) via microwave assisted heating treatment of arginine (Arg) and phosphoric acid. The Arg-CPDs exhibit bright blue fluorescence in aqueous solution and yellow green RTP emission in solid state, and the RTP emission is visible to the naked eye for about 4 s after switching-off the UV lamp. The phosphorescence lifetime of Arg-CPDs was 149 ms and 667 ms in ambient conditions and low temperature (77 K), respectively, which shown that the typical phosphorescent properties. Moreover, potential applications of the Arg-CPDs in the fields of information protection and encryption are demonstrated. This study provides a facile strategy for the preparation of matrix-free CPDs-based RTP materials toward the information security and their successful application in information security.
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