乙醇
乙烯
还原(数学)
电化学
化学
路径(计算)
有机化学
计算机科学
催化作用
电极
数学
物理化学
计算机网络
几何学
作者
Monsuru Olatunji Dauda,John Hendershot,Mustapha Bello,Junghyun Park,Alvaro Loaiza Orduz,Nicholas Lombardo,Orhan Kizilkaya,Phillip Sprunger,Anita Engler,Craig Plaisance,John Flake
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2024-02-23
标识
DOI:10.1149/1945-7111/ad2cc1
摘要
Abstract Ethylene is well known as the primary product of CO2 reduction at Cu electrocatalysts using zero-gap membrane electrode assembly cells with gas diffusion cathodes. Other types of Cu electrocatalysts including oxide-derived Cu, CuSn and CuSe yield relatively more C2 oxygenates; however, the mechanisms for C2 product selectivity are not well established. This work considers selectivity trends of Cu-P0.065, Cu-Sn0.03, and Cu2Se electrocatalysts made using a standard one pot synthesis method. Results show that Cu-P0.065 electrocatalysts (Cuδ+ = 0.13) retain ethylene as a primary product with relatively higher Faradaic efficiencies (FE = 43% at 350 mA cm-2) than undoped Cu electrocatalysts (FE = 31% at 350 mA cm-2) at the same current density. The primary CO2 reduction product at Cu-Sn0.03 (Cuδ+ = 0.27) electrocatalysts shifts to ethanol (FE = 48% at 350 mA cm-2) while CO2 reduction at Cu2Se (Cuδ+ = 0.47) electrocatalysts favor acetate production (FE = 40% at 350 mA cm-2). Based on these results, we propose a common acetyl intermediate and a mechanism for selective formation of ethylene, ethanol or acetate based on the degree of partial positive charge (δ+) of Cu reaction sites.
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