Beckmann rearrangements in bicyclo[2.2.1]heptan-2-one oximes
作者
Peter A. Hunt,Christopher J. Moody,Alexandra M. Z. Slawin,David J. Williams,Peter L. Myers,Colin Smith
出处
期刊:Perkin Transactions [Royal Society of Chemistry] 日期:1992-01-01卷期号: (7): 831-831被引量:5
标识
DOI:10.1039/p19920000831
摘要
Although Beckmann rearrangement of norcamphor oxime 1 was unsatisfactory, proceeding in poor yield to give a mixture of lactam products, rearrangement of the E/Z oxime 9, or the pure E-isomer 10, upon treatment with methanesulfonyl chloride and triethylamine, gave the lactam 12 in good yield.