金刚石顶砧
钻石
拉曼光谱
高压
校准
量具(枪械)
从头算
从头算量子化学方法
压力测量
材料科学
分析化学(期刊)
热力学
化学
光学
物理
冶金
量子力学
分子
有机化学
色谱法
作者
Natalia Dubrovinskaia,Leonid Dubrovinsky,Razvan Caracas,Michael Hanfland
摘要
A pressure gauge is a key issue of any high pressure experiment in a diamond anvil cell (DAC). Here we present a method of in situ synthesis of microcrystals of diamond that can be further used as a pressure standard in the course of the same DAC experiment. Calibration curve of the Raman shift versus pressure is extended up to 270 GPa and experimental results are compared with those of ab initio calculations.
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