Mononuclear Fe II and Heterobinuclear Fe II Ni II Thiolate Complexes Derived from a Compartmental Hexaazadithiophenolato Ligand: Synthesis, Structure and Properties

Compartmental macrocycles have proven to be very successful for the synthesis of heterobinuclear transition metal complexes. We obtained a mixed-ligand FeNi thiolate complex, [FeNiL(µ-OAc)]ClO 4 ( 3 ), where L 2- represents a 24-membered...