磷光
有机发光二极管
光化学
三苯胺
磷光有机发光二极管
电致发光
量子效率
荧光
光致发光
猝灭(荧光)
二苯胺
量子产额
材料科学
化学
分析化学(期刊)
光电子学
光学
物理
纳米技术
有机化学
图层(电子)
作者
Jingcheng Zhao,Xin Wang,Y. P. Liu,Zhiqiang Cheng,Xiaofu Wu,Hui Tong,Lixiang Wang
标识
DOI:10.1016/j.dyepig.2023.111842
摘要
Two selenoxanthen-9-one-based emitters (Se-2DPA and Se-2TPA) were synthesized by introducing diphenylamine and triphenylamine as electron donors. The doped films of Se-2DPA and Se-2TPA exhibited bright fluorescence-phosphorescence dual emission and comparable photoluminescence quantum yields (ΦPL) of 31.4 % and 29.6 %, respectively. Unlike the Se-2DPA with phosphorescence lifetime of 1.1 ms, Se-2TPA shows significantly extended phosphorescence lifetime up to 17.7 ms. As revealed by computational and experimental investigations, Se-2DPA maintained more effective spin orbit coupling (SOC) between T1 and S0 states and its radiative rate constant of phosphorescence is 1 order of magnitude higher than that of Se-2TPA, which resulted in a relatively shorter phosphorescence lifetime. Consequently, solution-processed organic light-emitting diodes (OLEDs) based on Se-2DPA with shorter phosphorescence lifetime achieved a maximum external quantum efficiency of 8.8 %, which is much higher than the device based on Se-2TPA (only 0.8 %). In contrast, Se-2TPA showed higher sensitivity for oxygen sensing and the Stern-Volmer quenching constant (KSV) value reached 3.04 × 10−3 ppm owing to the longer phosphorescence lifetime, which is over 3-folds higher than that of Se-2DPA (8.88 × 10−4 ppm) under the same conditions.
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