Biomimetic Mineralization Synthesis of Flower‐Like Cobalt Selenide/Reduced Graphene Oxide for Improved Electrochemical Deionization

Abstract Rationally and precisely tuning the composition and structure of materials is a viable strategy to improve electrochemical deionization (EDI) performances, which yet faces enormous challenges. Herein, an eco‐friendly biomimetic mineralization synthetic strategy is developed to synthesize the flower‐like cobalt selenide/reduced graphene oxide (Bio‐CoSe 2 /rGO) composites and used as advanced sodium ion adsorption electrodes. Benefiting from the slow and controllable reaction kinetics provided by the biomimetic mineralization process, the flower‐like CoSe 2 is uniformly constructed in the rGO, which is endowed with robust architecture, substantial adsorption sites and rapid charge/ion transport. The Bio‐CoSe 2 /rGO electrode yields the maximum salt adsorption capacity and salt adsorption rate of 56.3 mg g −1 and 5.6 mg g −1 min −1 respectively, and 92.5% capacity retention after 60 cycles. These results overmatch the pristine CoSe 2 and irregular granular CoSe 2 /rGO synthesized by a hydrothermal method, proving the structural superiority of the Bio‐CoSe 2 /rGO composites. Furthermore, the in‐depth adsorption kinetics study indicates the chemisorption nature of sodium ion adsorption. The structures of the Bio‐CoSe 2 /rGO composites after long term EDI cycles are intensively studied to unveil the mechanism behind such superior EDI performances. This study offers one effective method for constructing advanced EDI electrodes, and enriches the application of the biomimetic mineralization synthetic strategy.