In Situ Laser Direct Writing of Graphene-Based Layered Hybrid Materials with Superhydrophilicity

Laser-induced graphene (LIG) has attracted extensive attention as an electrode material. However, it usually exhibits limited electrochemical performance in many applications due to the limited electrical conductivity and charge storage properties. Herein, we proposed a simple and environmentally friendly strategy for in situ preparation of flexible Au/LIG/PI layered hybrid materials using laser direct writing. The transformation from hydrophobic to superhydrophilic of hybrid materials was successfully achieved. At a laser power of 6.0 W during laser reirradiation, the contact angle of the prepared Au/LIG/PI layered hybrid material was 0°. Characterizations confirmed a formed continuous Au layer covered on the porous LIG skeleton with a uniform distribution. The superhydrophilicity resulting from this unique microstructure greatly enhanced the electrochemical performance of the microsupercapacitors (MSCs) designed and fabricated based on Au/LIG/PI hybrid materials. Meanwhile, this MSC demonstrated excellent flexibility due to the PI substrate. The in situ preparation of superhydrophilic Au/LIG/PI layered hybrid materials provides a strategy for improving the performance of LIG-based MSCs, thereby enhancing their application potential.