Inverse NiO x ‐Ag Interface to Decouple Reactant Activation for Ag‐Ni/SiO 2 ‐Catalyzed Ester Hydrogenation

with ∼99% selectivity to MG over 500 h of continuous operation, among the highest reported for DMO hydrogenation. This work establishes interfacial inversion engineering as a versatile approach to optimize site complementarity in multi-step catalytic transformations.