Bimetal Metaphosphate/Molybdenum Oxide Heterostructure Nanowires for Boosting Overall Freshwater/Seawater Splitting at High Current Densities

Abstract Exploring excellent non‐noble bifunctional electrocatalysts for freshwater/seawater splitting at high current densities has attracted extensive interest owing to strong anodic oxidation and severe chloride corrosion challenges. Herein, hierarchical bimetal Ni‐Co metaphosphate/molybdenum oxide heterostructure nanowires (NiCoMoPO) are rationally designed and fabricated to efficiently boost oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in alkaline freshwater/seawater, where the favorable electronic structure from heterostructures, signified by X‐ray absorption spectra, endows NiCoMoPO with the enhanced intrinsic activity, while its hierarchical nanowire structure and heterostructures provide abundant active sites. Additionally, the PO 3 − improves the chloride‐corrosion resistance and efficiently facilitates the OER kinetics verified by theoretical and experimental studies. Therefore, NiCoMoPO drives 1000 mA cm −2 at low overpotentials of 467 and 442 mV for OER and HER in alkaline freshwater respectively, as well as a small cell voltage of 2.135 V for overall freshwater splitting with robust durability of 300 h. Impressively, due to the strong corrosion resistance, at 500 mA cm −2 of overall seawater splitting, NiCoMoPO maintains almost 2.096 V for 1200 h, indicating promising practical applications. This work sheds light on the rational design and fabrication of outstanding electrocatalysts at high current densities of seawater/freshwater splitting.