Rapid synthesis of sodium silicate through adiabatic reaction with low emission starting from exhausted KL-Si

硅酸钠 氢氧化钠 材料科学 硅酸盐 盐变质反应 放热反应 化学工程 废物管理 化学 冶金 有机化学 聚合 工程类 聚合物 复分解
作者
Wanvipa Pipathworapoom,Hsiao‐Ping Hsu,Kesavan Manibalan,C.W. Lan
出处
期刊:Journal of Cleaner Production [Elsevier BV]
卷期号:376: 134298-134298 被引量:1
标识
DOI:10.1016/j.jclepro.2022.134298
摘要

The kerf loss silicon (KL-Si) generated during the wafer slicing process in the photovoltaic industry is a resource that must be recycled. Compared to synthesizing sodium silicate from agricultural waste and other industrial methods, its synthesis from KL-Si has been very rare, but could be very effective. To recycle the industrial waste, a first-of-a-kind synthesis process of converting KL-Si into sodium silicate was developed. In this study, we presented a viable technique to synthesize sodium silicate from KL-Si waste by treating it with sodium hydroxide (NaOH) with a low water consumption rather than using conventional high-temperature techniques. The reaction occurred at elevated temperatures using its own exothermic reaction heat. Further, the modular number and sodium silicate concentration could be easily regulated, which resulted in an optimal conversion of the products. This synthetic method provided more than 98.5% conversion within an hour which was much higher and faster than the conventional methods. This synthesis method is highly efficient, eco-friendly, low emission, and low cost for rapid synthesis of sodium silicate. • Recycling of Kerf Loss silicon waste. • Synthesis of sodium silicate from Kerf Loss purified silicon • Cleaner and complete production sodium silicate product. • Reaction performed under mild reaction condition with near zero-emission. • Environmentally and economically beneficial for industrial use.
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