有机太阳能电池
透射率
光电子学
材料科学
不透明度
能量转换效率
载流子
吸收(声学)
聚合物
富勒烯
近红外光谱
可见光谱
光学
化学
有机化学
物理
复合材料
作者
Jung Won Yoon,Hyemin Bae,Jonghee Yang,Jong-Woon Ha,Changjin Lee,Jaewon Lee,Sung Cheol Yoon,Hyosung Choi,Seo-Jin Ko
标识
DOI:10.1016/j.cej.2022.139423
摘要
Semi-transparent organic solar cells (ST-OSCs) have attracted significant attention for various applications such as building-integrated photovoltaics and smart window technologies. Although various low-band gap non-fullerene acceptors have been developed, near-infrared (NIR) absorbing polymeric donors have been rarely reported for highly efficient ST-OSCs. In this study, we synthesize cyclopentadithiophene (CPDT) core-based NIR-absorbing polymer donors, PL1 and PL2. These polymer donors show strong NIR absorption capabilities with high transmittance in visible wavelength region and deep-lying HOMO levels for cascade energy level alignment with low-bandgap non-fullerene acceptors. The opaque device with PL2 and PCBM exhibits higher power conversion efficiency of 11.62% than that of the device with PL1 (PCE: 7.54%) due to lower charge-carrier recombination loss and balanced charge-carrier mobilities. Most significantly, incorporation of PL2 into ST-OSCs results in a PCE of 9.91 %, average visible transmittance of 40.4 % and light utilization efficiency (LUE) of 4.00 %. This work achieves the one of the highest LUE in ST-OSCs based on new NIR-absorbing polymer donors.
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