Role of Organic Matter, Mineral, and Rock Fabric in the Full-Scale Pore and Fracture Network Development in the Mixed Lacustrine Source Rock System

干酪根 地质学 碳酸盐 有机质 碎屑岩 粘土矿物 自生的 沉积岩 总有机碳 碳酸盐矿物 矿物学 烃源岩 地球化学 方解石 地貌学 化学 环境化学 构造盆地 有机化学
作者
Guangqing Yang,Jianhui Zeng,Juncheng Qiao,Yazhou Liu,Shengnan Liu,Wanting Jia,Weifu Cao,Chengyun Wang,Feng Geng,Wenfei Wei
出处
期刊:Energy & Fuels [American Chemical Society]
卷期号:36 (15): 8161-8179 被引量:8
标识
DOI:10.1021/acs.energyfuels.2c01484
摘要

The mixed deposition constitutes the external clastic, intrabasinal, and pyroclastic components in both marine and lacustrine environments. The fine-grained mixed lacustrine source rocks are rich in organic matter and present good unconventional energy resources. However, the mixed lacustrine source rock systems have extremely low permeabilities and need hydraulic fracturing to stimulate oil from the complex nanoscale matrix. The role of rock fabric, organic matter, and mineral compositions in full-scale pore structures is still unclear, especially for the source rock from a mixed sedimentary environment. This restricts sweet spot identification. Here, we use three groups of Permian Lucaogou source rock samples with fine laminated, thick laminated, and massive rock fabric to investigate the relationship between rock fabric, organic matter, and pore structure using a combination of mineralogy, organic geochemistry, low-pressure nitrogen adsorption, micro-CT, and mercury injection capillary pressure data. The results indicate that the Lucaogou source rocks mainly contain type I and type II kerogen and show good to excellent hydrocarbon generation potential. The source rock was deposited in a mixed environment with high contents of carbonate and less siliceous minerals, showing good frackability. The mineralogy-based ternary classification shows that the source rock mainly belongs to high total organic carbon (TOC > 4%) mixed carbonate mudstone and high TOC mixed mudstone. For mixed lacustrine source rock, the full-scale pore-fracture distribution shows that the average percentage values of pore volume for micropores (<10 nm), transitional pores (10–100 nm), mesopores (100–1000 nm), and macropores (fracture) (>1000 nm) are 11.14, 21.62, 10.77, and 56.47%, respectively. However, the average percentage values of pore surface area for the abovementioned pores are 62.45, 30.45, 5.47, and 1.63%, respectively. Both quartz and terrigenous clast present a weak-medium unimodal correlation with the TOC content. Both terrigenous clast and clay minerals control the source rock hydrocarbon generation potential. The carbonate and terrigenous clast mineral content play a significant role in micropores and transitional pores, while the clay mineral presents a negative impact on macropore development. The effect of rock fabric on shale oil potential is negligible compared with organic matter abundance. Shales with thick parallel laminae and medium TOC (2% < TOC < 4%) possess favorable shale oil potential.
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