Occurrence and spatial distribution of trace metals in seawaters of the Drake Passage and Antarctic Peninsula

In this study, surface seawater was collected from 82 stations in the Drake Passage and Antarctic Peninsula sea area, and the distribution characteristics and correlations of 11 trace elements (i.e., V, Cr, Mn, Co, Cu, Zn, As, Mo, Cd, Pb, and U) in the seawater were analyzed. Results showed remarkable differences in the concentration of different elements, among which those of Mn (53.15%), Mo (22.77%), Zn (9.81%), and U (6.23%) were relatively high. The concentration of trace elements in Drake Passage water was relatively low, likely because a westerly drift that enhances large circulating currents exists in the sea area, thereby affecting the distribution of substances in the water. Mn, Co, Cu, Zn, Cd, and Pb showed relatively high concentrations at more stations than the other elements, and the high concentrations of Mn, Co, and Cd were mainly found in shallow water areas. UV, MoV, AsV, AsMo, AsU, and MoU demonstrated good linear correlations with correlation coefficients in the range of 0.878-0.961. These results could provide support for further explorations of the environmental behavior of trace elements in Antarctica.