Protrudent Iron Single‐Atom Accelerated Interfacial Piezoelectric Polarization for Self‐Powered Water Motion Triggered Fenton‐Like Reaction

Abstract Water in motion presented in natural systems contains a rich source of renewable mechanical energy. Harvesting this water energy to trigger the generation of reactive oxygen species (ROS) for water purification is a desirable yet underexplored solution. Herein, the authors report a self‐powered water motion triggered Fenton‐like reaction system for wastewater treatment through the piezo‐activation of peroxymonosulfate (PMS). Isolated protrudent Fe single atomic sites are immobilized on the surface of molybdenum disulfide (MoS 2 ) nanosheet to improve piezoelectric polarization of MoS 2 , to accelerate piezoelectric charge separation, and to enhance PMS activation for water purification. ROS ( • OH, SO 4 •− , O 2 •− , and 1 O 2 ) generation for PMS piezo‐activation are observed, and different water contaminants, including antibiotic, industrial chemicals, and dyes are efficiently removed under the natural water fluid. Aimed at solving concurrent issues of environmental pollution and energy crisis, this study provides a pathway for single atomic‐mediated piezo‐activation of Fenton‐like reactions through ambient self‐powered water motion for water purification.