Simulation of the electrocatalytic activity of cobalt for hydrogen evolution reaction was performed in 1 M NaOH solution. The simulation of current – potential correlation was performed using the SigmaPlot program. For Tafel slope of -115 mV dec -1 and exchange current density of 5.6×10 -6 A cm -2 , a linear polarization response for cobalt was modelled. Simulation of cobalt impedance spectra in 1 M NaOH solution was also performed, using the ZView program. Electrochemical impedance spectra were modelled using Randles simple electrical equivalent circuit and presented in form of Nyquist and Bode plot. From these experimental data, electrode surface roughness, exchange current density and Tafel slope were derived.