木质素
PEG比率
软木
聚乙二醇
化学
生物量(生态学)
木质纤维素生物量
溶剂分解
大小排阻色谱法
凝胶渗透色谱法
热重分析
解聚
溶剂
有机化学
化学工程
制浆造纸工业
聚合物
水解
酶
经济
工程类
地质学
海洋学
财务
作者
Thi Thi Nge,Yuki Tobimatsu,Shiho Takahashi,Eri Takata,Masaomi Yamamura,Yasuyuki Miyagawa,Tsutomu Ikeda,Toshiaki Umezawa,Takatoshi Yamada
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2018-05-14
卷期号:6 (6): 7841-7848
被引量:24
标识
DOI:10.1021/acssuschemeng.8b00965
摘要
We have developed an environmentally benign large-scale (50 kg wood meal per batch) lignin production plant, operating based on acid-catalyzed polyethylene glycol (PEG) solvolysis of softwood biomass. The motivation for the proposed process was to promote technological innovation in biomass utilization systems in Japanese rural areas based on widely abundant Japanese cedar (sugi) biomass. In this study, the process was evaluated by investigating the effects of the source sugi wood meal size and the solvent PEG molecular mass on the yield, chemical structure, molecular mass, and thermal properties of the resultant PEG-modified lignin derivatives, glycol lignins (GLs). Reducing the source wood meal size and PEG solvent molecular mass not only promoted lignin PEGylation but also the subsequent acid-induced chemical rearrangements of the GLs as demonstrated by chemical analyses, 2D NMR, and size exclusion chromatography (SEC). Reducing the source wood meal size and/or increasing the solvent PEG molecular mass enhanced the thermal properties of GLs as determined by thermomechanical analysis (TMA) and thermogravimetric analysis (TGA). We considered that the proposed process can efficiently produce lignin derivatives with substantial control over the chemical structure and thermal properties to meet commercial and industrial needs for lignin-based advanced material production.
科研通智能强力驱动
Strongly Powered by AbleSci AI