超级电容器
电解质
电容
活性炭
材料科学
共晶体系
深共晶溶剂
微型多孔材料
乙二醇
化学工程
碳纤维
介孔材料
电极
去壳
堆栈(抽象数据类型)
化学
复合材料
有机化学
复合数
吸附
计算机科学
微观结构
工程类
物理化学
催化作用
程序设计语言
生物
植物
作者
Sethuraman Sathyamoorthi,Nutthaphon Phattharasupakun,Montree Sawangphruk
标识
DOI:10.1016/j.electacta.2018.08.027
摘要
Deep eutectic solvents (DESs) have been emerging as newer environmentally benign electrolytes for energy storage devices with the high-temperature operational capability. For the first-time, we propose ethylene glycol and tetrapropylammonium bromide based non-fluoro DESs as electrolytes for the supercapacitor. Different compositions of DESs were also evaluated. Also, the high-temperature operational capability of the proposed electrolytes was evaluated with the free-standing microporous commercial activated carbon (AC) and mesoporous rice husk-derived bio-activated carbon (Bio-AC). The maximum cell voltages of 1.3 V and 1.0 V are identified for AC and Bio-AC based supercapacitors, respectively at 25 °C. The specific capacitances of both AC and Bio-AC electrodes are ∼100 F g−1 at 0.1 A g−1. The proposed DES electrolyte can be operated at the maximum temperature of 115 °C, which is higher than the previously reported DESs (80 °C). The specific capacitance increases with increasing temperature, and the maximum specific capacitance of an electrode is 172 F g−1 at 115 °C for Bio-AC supercapacitor. Excellent long-term stability is noted after 10,000 cycles at 25 °C and 115 °C for both AC and Bio-AC supercapacitors. The supercapacitors here may be practically used in high-temperature applications.
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