Intercalated Water and Organic Molecules for Electrode Materials of Rechargeable Batteries

Abstract The intrinsic limitations of lithium‐ion batteries (LIBs) with regard to safety, cost, and the availability of raw materials have promoted research on so‐called “post‐LIBs”. The recent intense research of post‐LIBs provides an invaluable lesson that existing electrode materials used in LIBs may not perform as well in post‐LIBs, calling for new material designs compliant with emerging batteries based on new chemistries. One promising approach in this direction is the development of materials with intercalated water or organic molecules, as these materials demonstrate superior electrochemical performance in emerging battery systems. The enlarged ionic channel dimensions and effective shielding of the electrostatic interaction between carrier ions and the lattice host are the origins of the observed electrochemical performance. Moreover, these intercalants serve as interlayer pillars to sustain the framework for prolonged cycles. Representative examples of such intercalated materials applied to batteries based on Li+, Na+, Mg2+, and Zn2+ ions and supercapacitors are considered, along with their impact in materials research.