Morphological characterization, thermal, and mechanical properties of compatibilized high density polyethylene/polystyrene/organobentonite ternary nanocomposites

Abstract Composite materials made from high density polyethylene (HDPE) and polystyrene (PS) were successfully prepared in different HDPE/PS weight ratios, by melt mixing 3 wt% of bentonite clay organically modified with hexadecyl ammonium chloride (organo-modified bentonite, OBT). The structure and morphology of these composites were examined by X-ray diffraction and scanning electron microscopy. Morphological changes between the composite and the constituent materials were observed. The decrease in PS (or HDPE) particle size in HDPE/PS 70/30 (or 30/70) that blend after the OBT addition reflects a clear improvement in the HDPE/PS blend compatibility. The effect of OBT on the thermal and mechanical properties was investigated by differential scanning calorimetry, thermogravimetric analysis, and tensile measurements. The main results show a decrease in the HDPE crystallinity in the composite matrices, which reaches 25% for HDPE/PS/OBT 29/68/3 composite, also an improvement of the thermal stability, as evidenced by the higher T onset values, and finally a reinforcement of the tensile properties as compared to the unfilled blends. Indeed, a significant enhancement of the tensile modulus (~130%) is observed for the 68/29/3 composite matrix as compared to the 70/30 unfilled blend.