The Hydrothermal Synthesis of Porous Material MOF Based on the CMIA-Cd

本论文利用羧酸类配体CMIA和Cd，利用溶剂热反应，构筑了一个新的稳定的三维MOF孔道材料。结构分析表明该配合物属单斜晶系，空间群均为P21/n，a = 8.1153(4) A，b = 22.3470(9) A，c = 25.348(3) A；α = 90˚，β = 99.4500(10)˚，γ = 90˚，V = 3151.4(2) A3，并利用红外分析探讨了框架的相互作用。 In this paper, pyridine carboxylic acid ligands CMIA and transition meta Cd, thermal reaction with a solvent were used to build a new stable three-dimensional pore MOF materials. Structural analysis shows that the compound belongs to the monoclinic system, space group are P21/n, a = 8.1153(4) A, b = 22.3470(9) A, c = 25.348(3) A, α = 90˚, β = 99.4500(10)˚, γ = 90˚, V = 3151.4(2) A3, and IR analy-sis was used to explore the MOFs interaction and stability.