聚氨酯
染色
纳米复合材料
傅里叶变换红外光谱
材料科学
有机粘土
高分子化学
透射电子显微镜
化学工程
酸性染料
纺纱
形态学(生物学)
化学
复合材料
纳米技术
工程类
生物
遗传学
作者
G. V. Raghunath Reddy,Mangala Joshi,Bapan Adak,B. L. Deopura
摘要
Polyurethane/clay nanocomposite ( PUCN ) filaments were spun by the dry‐jet‐wet spinning method. To prepare the PUCN filaments, 0.25, 0.50 and 1% of nanoclay on the weight of polyurethane were incorporated in the polyurethane dope. The interaction between clay and polyurethane was analysed by attenuated total reflectance–Fourier Transform‐infrared ( ATR ‐ FTIR ) spectroscopy. The structure and morphology of the PUCN filaments were analysed by wide‐angle X‐ray diffraction ( WAXD ) and transmission electron microscopy ( TEM ). Both the neat polyurethane and the PUCN filaments were dyed with different acid, basic and reactive dyes. The neat polyurethane filaments exhibited poor dyeability with all three classes of dyes. By contrast, the PUCN filaments showed a significantly higher dye uptake with all of the dyes used. Furthermore, the dye uptake increased significantly as the percentage of clay in the filaments increased, as indicated by the increase in the K/S values of the dyed filaments. The dyeing mechanism with all three dyes, as well as the increased dyeability of the PUNC filaments in comparison to those of the neat polyurethane filaments, was discussed.
科研通智能强力驱动
Strongly Powered by AbleSci AI