Ethers and esters as alternative fuels for internal combustion engine: A review

Ether and ester fuels can work in the existing internal combustion (IC) engine with some important advantages. This work comprehensively reviews and summarizes the literatures on ether fuels represented by DME, DEE, DBE, DGM, and DMM, and ester fuels represented by DMC and biodiesel from three aspects of properties, production and engine application, so as to prove their feasibility and prospects as alternative fuels for compression ignition (CI) and spark ignition (SI) engines. These studies cover the effects of ether and ester fuels applied in the form of single fuel, mixed fuel, dual-fuel, and multi-fuel on engine performance, combustion and emission characteristics. The evaluation indexes mainly include torque, power, BTE, BSFC, ignition delay, heat release rate, pressure rise rate, combustion duration, exhaust gas temperature, CO, HC, NO x , PM, and smoke. The results show that ethers and esters have varying degrees of impact on engine performance, combustion and emissions. They can basically improve the thermal efficiency of the engine and reduce particulate emissions, but their effects on power, fuel consumption, combustion process, and CO, HC, and NO x emissions are uncertain, which is due to the coupling of operating conditions, fuel molecular structure, in-cylinder environment and application methods. By changing the injection strategy, adjusting the EGR rate, adopting a new combustion mode, adding improvers or synergizing multiple fuels, adverse effects can be avoided and the benefits of oxygenated fuel can be maximized. Finally, some challenges faced by alternative fuels and future research directions are analyzed.