Three-dimensional hierarchical oxygen vacancy-rich WO3-decorated Ni foam evaporator for high-efficiency solar-driven interfacial steam generation

• A novel 3D hierarchical WO 3−x /NF solar steam generation device was successfully fabricated. • The WO 3−x /NF evaporator exhibited a high and stable solar steam evaporation rate. • The DFT results reveal that the WO 3 with oxygen vacancies possess a narrower bandgap. Solar steam generation is considered to be an effective strategy to alleviate the global water shortage problem. Therefore, exploring highly efficient and thermal stability photothermal conversion materials is highly essential and urgent. In this work, we develop a three-dimensional (3D) oxygen vacancy-rich WO 3 with ‘‘nanorod array grown on nanosheet array” unique architecture decorated on Ni foam (denoted as WO 3−x /NF) through a simple and effective hydrothermal method followed by an annealing route, which is applied as light-absorbing material. The 3D hierarchical porous unique structure of the WO 3−x /NF evaporator can supply a channel steam escaping and enhance the light trapping due to the multi-scattering effect, and the localized surface plasmon resonance (LSPR) effects of WO 3−x also contribute to increase the light absorption in the full solar spectrum. The as-prepared WO 3−x /NF evaporator reveals a high solar absorption (95%), an evaporation rate of 1.50 kg m −2 h −1 under one sun illumination, and a light-to-heat conversion efficiency of about 88%, as well as stable salt-resistance performance. The water purification results show that WO 3−x /NF evaporator has a significant effect on seawater desalination without significant salt accumulation and purification of heavy metal wastewater. Furthermore, the first-principles calculations reveal that WO 3 with oxygen vacancies has a narrower bandgap, which is more conducive to absorb solar energy from the whole spectrum. This work can provide a new avenue toward the design of other high photothermal conversion system.