纤维素
材料科学
气凝胶
可燃性
纳米技术
热稳定性
聚合物
制作
材料设计
化学工程
复合材料
医学
工程类
病理
替代医学
作者
Vahid Rahmanian,Tahira Pirzada,Siyao Wang,Saad A. Khan
标识
DOI:10.1002/adma.202102892
摘要
The brittle nature of early aerogels developed from inorganic precursors fueled the discovery of their organic counterparts. Prominent among these organics are cellulose aerogels because of their natural abundance, biocompatibility, sustainable precursors, and tunable properties. The hierarchical structure of cellulose, from polymers to nano/microfibers, further facilitates fabrication of materials across multiple length scales with added applicability. However, the inherent flammability, structural fragility, and low thermal stability have limited their use. Recently developed cellulose-based hybrid aerogels offer strong potential owing to their tunability and enhanced functionality brought about by combining the inherent properties of cellulose with organic and inorganic components. A survey of the historical background and scientific achievements in the design and development of cellulose-based hybrid aerogel materials is encompassed here. The impacts of incorporating organic and inorganic ingredients with cellulose and the corresponding synergistic effects are discussed in terms of their design and functionality. The underlying principles governing the structural integration and functionality enhancement are also analyzed. The latest developments of cellulose-based hybrid aerogels fabricated from nontraditional incipient aerogels, such as fibrous webs, are also explored. Finally, future opportunities that could make these materials achieve even greater impacts through improved scalability, rationally designed synthesis, and multifunctional properties are discussed.
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