化学
铜
催化作用
苯乙烯
联轴节(管道)
光化学
可见光谱
组合化学
有机化学
光电子学
共聚物
冶金
物理
材料科学
聚合物
作者
xiao-jing xu,Zhuomin Chi,Rui Ren,Zhe Zhang,H. Li,Xue-Yuan Liu
标识
DOI:10.1002/adsc.202400116
摘要
Transition‐metal catalyzed difunctionalization of olefins has attracted considerable attention as a method to construct carbon‐carbon and carbon‐hetero bonds. Herein, the copper‐catalyzed three‐component radical cross‐coupling of oxime esters, styrenes, and AgSCF3 through a visible‐light‐promoted iminyl radical‐mediated carbon‐carbon bond cleavage strategy has been described. Utilizing low‐cost copper salt as both photosensitizers and cross‐couplers, this protocol delivers diverse target products, providing a supplementary approach for cyanoalkylation and trifluoromethylthiolation of drug molecules.
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