阳极
腐蚀
锌
电解质
电偶阳极
材料科学
无机化学
化学
冶金
电极
阴极保护
物理化学
作者
Haohan Li,Yunhua Gan,Jie Zeng,Mengting Lv,Bo Shang,Wenpo Li
标识
DOI:10.1016/j.corsci.2023.111544
摘要
Zinc metal anodes offer low-cost and safe options for energy storage. However, the corrosion and dendritic growth limit battery longevity. In this study, a trace amount of 6-bromo-1 H-benzimidazole (BHB) is introduced as an electrolyte additive. Experimental and theoretical results demonstrate that BHB molecules adsorb on the zinc anode, suppressing corrosion, secondary reactions, and dendritic growth. BHB demonstrates exceptional corrosion inhibition (99.1%). BHB enables stable cycling of zinc anode for over 1150 h at 5 mA cm−2 and exhibits excellent zinc anode reversibility in Zn||Cu half-cells (CE=99.24%). This research provides an encouraging pathway for zinc anode electrolyte additives.
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