An Ultra‐Flexible Sodium‐Ion Full Cell with High Energy/Power Density and Unprecedented Structural Stability

Abstract Futuristic wearable electronics desperately need power sources with similar flexibility and durability. In this regard, the authors, therefore, propose a scalable PAN‒PMMA blend‐derived electrospinning protocol to fabricate free‐standing electrodes comprised of cobalt hexacyanoferrate nanocube cathode and tin metal organic framework‐derived nanosphere anode, respectively, for flexible sodium‐ion batteries. The resulting unique inter‐networked nanofiber mesh offers several advantages such as robust structural stability towards repeated bending and twisting stresses along with appreciable electronic/ionic conductivity retention without any additional post‐synthesis processing. The fabricated flexible sodium ion full cells deliver a high working voltage of 3.0 V, an energy density of 273 Wh·kg −1 , and a power density of 2.36 kW·kg −1 . The full cells retain up to 86.73% of the initial capacity after 1000 cycles at a 1.0 C rate. After intensive flexibility tests, the full cells also retain 78.26% and 90.78% of the initial capacity after 1000 bending and twisting cycles (5 mm radius bending and 40 o axial twisting), respectively. This work proves that the proposed approach can also be employed to construct similar robust, free‐standing nanofiber mesh‐based electrodes for mass‐producible, ultra‐flexible, and durable sodium ion full cells with commercial viability.