Aging of polystyrene microplastics by UV/Sodium percarbonate oxidation: Organic release, mechanism, and disinfection by-product formation

The occurrence and transformation of microplastics (MPs) in environment has attracted considerable attention. However, the release characteristics of MP-derived dissolved organic matter (MP-DOM) under oxidation conditions and the effect of DOM on subsequent chlorination disinfection by-product (DBP) still lacks relevant information. This study focused on the conversion of polystyrene microplastics (PSMPs) in the advanced oxidation of ultraviolet-activated sodium percarbonate (UV/SPC-AOP) and the release characteristics of MP-DOM. The DBP formation potential of MP-DOM was also investigated. As a result, UV/SPC significantly enhanced the aging and fragmentation of PSMPs. Under UV irradiation, the fluorescence peak intensity and position of humus-like and protein-like components of MP-DOM were correlated with SPC concentration. The aging MP suspension was analyzed by gas chromatography-mass spectrometry (GC-MS), and various alkyl-cleavage and oxidation products were identified. Quenching experiments and electron paramagnetic resonance (EPR) detection confirmed that carbonate and hydroxyl radicals jointly dominated the conversion of PSMPs. The formation of DBP was related to the components of MP-DOM. Overall, these results help to understand the aging behavior of MPs in AOP. Moreover, MP-DOM released by MPs after AOP oxidation may be a precursor of DBPs, which deserved more attention.