Sulfur defect induced Cd0.3Zn0.7S in-situ anchoring on metal organic framework for enhanced photothermal catalytic CO2 reduction to prepare proportionally adjustable syngas

The rapid recombination of interfacial charges is considered to be the main obstacle limiting the photocatalytic CO2 reduction. Thus, it is a challenge to research an accurate and stable charge transfer control strategy. MIL-53 (Al)-S/Cd0.3Zn0.7S (MAS/CZS-0.3) photocatalysts with chemically bonded interfaces were constructed by in-situ electrostatic assembly of sulfur defect Cd0.3Zn0.7S (CZS-0.3) on the surface of MIL-53 (Al) (MAW), which enhanced interfacial coupling and accelerated electron transfer efficiency. An adjustable proportion of syngas (H2/CO) was prepared by photothermal catalytic CO2 reduction at micro-interface. and the optimal yield of CO (66.10 μmol∙g-1∙h-1) and H2 (71.0 μmol∙g-1∙h-1) was realized by the MAS/CZS-0.3 photocatalyst. The improved activity was due to the photogenerated electrons migrated from CZS-0.3 to the adsorption active sites of MAS, which strengthened the adsorption and activation of CO2 on MAS. The photothermal catalytic CO2 reduction to CO follows the pathway of CO2→*COOH → CO and CO2→*HCO3-→CO. This work provided a reference for the research, characterization, and application of in-situ anchoring of metal organic frameworks in photothermal catalytic CO2 reduction, and provided a green path for the supply of Syngas in industry.